Investigations of Low-Symmetrical Tetraaryltetrabenzoporphyrins Produced by Mixed Condensation Reactions

Ruppel M, Gazetas LP, Lungerich D, Hampel F, Jux N (2020)

Publication Type: Journal article

Publication year: 2020

Journal

Journal of Organic Chemistry American Chemical Society

Book Volume: 85

Pages Range: 7781-7792

Journal Issue: 12

DOI: 10.1021/acs.joc.0c00293

Abstract

Within the past decade, tetraaryltetrabenzoporphyrins (TATBPs) have gained rising attention due to their potential in various fields of materials science and medicinal chemistry. However, this class of compounds still lacks in structural diversity, especially in the case of low-symmetrical compounds. Herein, mixed condensations were utilized to generate TATBPs with different substituents either in the meso-positions or the periphery of the macrocycle with total yields of 55-58%. The separation of crude mixtures was achieved by feasible chromatographic purification. The influence of symmetry on the electronic properties of TATBPs was studied by optical spectroscopy, electrochemistry, and X-ray diffraction.

Authors with CRIS profile

Michael Ruppel Lehrstuhl für Organische Chemie II Lampros-Pascal Gazetas Lehrstuhl für Organische Chemie II Dominik Lungerich Lehrstuhl für Organische Chemie II Frank Hampel Lehrstuhl für Organische Chemie I Norbert Jux Interdisziplinäres Zentrum für Molekulare Materialien

How to cite

APA:

Ruppel, M., Gazetas, L.-P., Lungerich, D., Hampel, F., & Jux, N. (2020). Investigations of Low-Symmetrical Tetraaryltetrabenzoporphyrins Produced by Mixed Condensation Reactions. Journal of Organic Chemistry, 85(12), 7781-7792. https://doi.org/10.1021/acs.joc.0c00293

MLA:

Ruppel, Michael, et al. "Investigations of Low-Symmetrical Tetraaryltetrabenzoporphyrins Produced by Mixed Condensation Reactions." Journal of Organic Chemistry 85.12 (2020): 7781-7792.

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