Sulphur tolerant diesel oxidation catalysts by noble metal alloying

Franken T, Vieweger E, Klimera A, Hug M, Heel A (2019)


Publication Type: Journal article

Publication year: 2019

Journal

Book Volume: 129

Article Number: 105732

DOI: 10.1016/j.catcom.2019.105732

Abstract

A series of Mn-alloyed Pt supported catalysts were investigated for the NO oxidation reaction applied in diesel oxidation catalysts under sulphur-containing conditions. The observed NO oxidation conversion correlated to the Pt amount in the catalyst under sulphur-free conditions. In the presence of SO2 in the feed, the Pt/Al2O3 catalyst heavily deactivated resulting in the lowest performance compared to Mn-alloyed Pt catalysts. Already small amounts of Mn improved the SO2-resistance significantly. Whilst pure Pt/Al2O3 catalyst deactivates fully within the first 30 min under NO oxidation conditions including 300 ppm SO2, an alloy with a Mn to Pt ratio of 1:1 performed with a remarkable high catalytic stability for the NO oxidation over at least 70 h under continuous testing conditions.

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APA:

Franken, T., Vieweger, E., Klimera, A., Hug, M., & Heel, A. (2019). Sulphur tolerant diesel oxidation catalysts by noble metal alloying. Catalysis Communications, 129. https://dx.doi.org/10.1016/j.catcom.2019.105732

MLA:

Franken, Tanja, et al. "Sulphur tolerant diesel oxidation catalysts by noble metal alloying." Catalysis Communications 129 (2019).

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