Photocyclization of diarylethylenes with a boronate moiety: a useful synthetic tool to soluble PAH building blocks

Feofanov M, Uka A, Akhmetov V, Amsharov K (2020)

Publication Type: Journal article

Publication year: 2020

Journal

Photochemical & Photobiological Sciences Royal Society of Chemistry

Book Volume: 19

Pages Range: 722-725

Journal Issue: 5

DOI: 10.1039/c9pp00497a

Abstract

The synthesis of ten ortho-fused PAHs bearing boronic pinacol ester groups (BPin) is reported. The products are obtained via modification of Mallory photocyclization in 45-99% yields. Among them are examples of highly strained molecules such as [4]helicene derivatives with BPin substituents in the cavity. The method allows double C-C coupling and tolerates more than one BPin functionality.

Authors with CRIS profile

Mikhail Feofanov Lehrstuhl für Organische Chemie II Arber Uka Lehrstuhl für Organische Chemie II Vladimir Akhmetov Lehrstuhl für Organische Chemie II Konstantin Amsharov Lehrstuhl für Organische Chemie II

How to cite

APA:

Feofanov, M., Uka, A., Akhmetov, V., & Amsharov, K. (2020). Photocyclization of diarylethylenes with a boronate moiety: a useful synthetic tool to soluble PAH building blocks. Photochemical & Photobiological Sciences, 19(5), 722-725. https://doi.org/10.1039/c9pp00497a

MLA:

Feofanov, Mikhail, et al. "Photocyclization of diarylethylenes with a boronate moiety: a useful synthetic tool to soluble PAH building blocks." Photochemical & Photobiological Sciences 19.5 (2020): 722-725.

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