Conformal Cu2S-coated Cu2O nanostructures grown by ion exchange reaction and their photoelectrochemical properties
Minguez-Bacho I, Courte M, Fan HJ, Fichou D (2015)
Publication Status: Published
Publication Type: Journal article
Publication year: 2015
Journal
Publisher: IOP PUBLISHING LTD
Book Volume: 26
Article Number: ARTN 185401
Journal Issue: 18
DOI: 10.1088/0957-4484/26/18/185401
Abstract
Cuprous oxide Cu2O is a promising p-type semiconductor for photoelectrochemical (PEC) solar hydrogen generation because it has a suitable bandgap (E-g = 2.0-2.2 eV) and a band alignment adapted to water reduction. In addition, metallic Cu is earth-abundant thus making Cu2O a low-cost material. However, the reduction potential of Cu2O into metallic Cu (0.47 V versus RHE) is lower than that of water which induces a severe instability under irradiation in a PEC cell. Therefore, our recent efforts focused on the growth of a protective overlayer on top of Cu2O in order to stabilize Cu2O when used as a photocathode in an aqueous electrolyte. Among potential protective materials cuprous sulphide Cu2S is another p-type semiconductor with a 1.2 eV bandgap and an appropriate energy level alignment with Cu2O that would allow electrons flowing to the interface. We present here an original and simple method aimed at protecting a compact layer (CL) or nanowires (NWs) of Cu2O with a Cu2S coating. Our method is based on the ions exchange reaction (IER) of O2- into S2- at the surface of Cu2O itself in a solution-containing Na2S as the sulphur source. The local surface IER implies the formation of a conformal and uniform coating independently on the starting Cu2O morphology, CLs or NWs. As expected, coating Cu2O photocathodes by a conformal Cu2S layer improves their stability and PEC performances.
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APA:
Minguez-Bacho, I., Courte, M., Fan, H.J., & Fichou, D. (2015). Conformal Cu2S-coated Cu2O nanostructures grown by ion exchange reaction and their photoelectrochemical properties. Nanotechnology, 26(18). https://dx.doi.org/10.1088/0957-4484/26/18/185401
MLA:
Minguez-Bacho, Ignacio, et al. "Conformal Cu2S-coated Cu2O nanostructures grown by ion exchange reaction and their photoelectrochemical properties." Nanotechnology 26.18 (2015).
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