Solvent-Controlled Polymerization of Molecular Strontium Vanadate Monomers into 1D Strontium Vanadium Oxide Chains

Schwarz B, Dürr M, Kastner K, Heber N, Ivanovic-Burmazovic I, Streb C (2019)


Publication Type: Journal article

Publication year: 2019

Journal

Book Volume: 58

Pages Range: 11684-11688

Journal Issue: 17

DOI: 10.1021/acs.inorgchem.9b01665

Abstract

We report the polymerization of a solvent-stabilized molecular strontium vanadium oxide monomer into infinite 1D chains. Supramolecular polymerization is triggered by controlled solvent-exchange, which leads to oligomer and polymer formation. Mechanistic insights into the chain formation were obtained by solid-state, solution, and gas-phase studies. The study shows how reactivity control of molecular metal oxides can be used to assemble complex inorganic polymeric structures.

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APA:

Schwarz, B., Dürr, M., Kastner, K., Heber, N., Ivanovic-Burmazovic, I., & Streb, C. (2019). Solvent-Controlled Polymerization of Molecular Strontium Vanadate Monomers into 1D Strontium Vanadium Oxide Chains. Inorganic Chemistry, 58(17), 11684-11688. https://doi.org/10.1021/acs.inorgchem.9b01665

MLA:

Schwarz, Benjamin, et al. "Solvent-Controlled Polymerization of Molecular Strontium Vanadate Monomers into 1D Strontium Vanadium Oxide Chains." Inorganic Chemistry 58.17 (2019): 11684-11688.

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