Solvent-Controlled Polymerization of Molecular Strontium Vanadate Monomers into 1D Strontium Vanadium Oxide Chains

Schwarz B, Dürr M, Kastner K, Heber N, Ivanovic-Burmazovic I, Streb C (2019)

Publication Type: Journal article

Publication year: 2019

Journal

Inorganic Chemistry American Chemical Society

Book Volume: 58

Pages Range: 11684-11688

Journal Issue: 17

DOI: 10.1021/acs.inorgchem.9b01665

Abstract

We report the polymerization of a solvent-stabilized molecular strontium vanadium oxide monomer into infinite 1D chains. Supramolecular polymerization is triggered by controlled solvent-exchange, which leads to oligomer and polymer formation. Mechanistic insights into the chain formation were obtained by solid-state, solution, and gas-phase studies. The study shows how reactivity control of molecular metal oxides can be used to assemble complex inorganic polymeric structures.

Authors with CRIS profile

Maximilian Dürr Lehrstuhl für Bioanorganische Chemie Ivana Ivanovic-Burmazovic Lehrstuhl für Bioanorganische Chemie

Involved external institutions

Universität Ulm DE Germany (DE)

How to cite

APA:

Schwarz, B., Dürr, M., Kastner, K., Heber, N., Ivanovic-Burmazovic, I., & Streb, C. (2019). Solvent-Controlled Polymerization of Molecular Strontium Vanadate Monomers into 1D Strontium Vanadium Oxide Chains. Inorganic Chemistry, 58(17), 11684-11688. https://doi.org/10.1021/acs.inorgchem.9b01665

MLA:

Schwarz, Benjamin, et al. "Solvent-Controlled Polymerization of Molecular Strontium Vanadate Monomers into 1D Strontium Vanadium Oxide Chains." Inorganic Chemistry 58.17 (2019): 11684-11688.

BibTeX: Download