Configurationally Stable Chiral Dithia-Bridged Hetero[4]helicene Radical Cation: Electronic Structure and Absolute Configuration

Gliemann B, Petrovic AG, Zolnhofer E, Dral PO, Hampel F, Breitenbruch G, Schulze P, Raghavan V, Meyer K, Polavarapu PL, Berova N, Kivala M (2017)

Publication Type: Journal article

Publication year: 2017

Journal

Book Volume: 12

Pages Range: 31-35

Journal Issue: 1

DOI: 10.1002/asia.201601452

Abstract

A stable chiral hetero[4]helicene radical cation was synthesized and characterized by UV/Vis absorption and EPR spectroscopy, as well as X-ray crystallography. For the first time, a combination of chiroptical methods involving ECD, ORD, and VCD, supported by quantum mechanical predictions, enabled the elucidation of the absolute configuration of such open-shell helical species.

Authors with CRIS profile

Additional Organisation(s)

Involved external institutions

Max-Planck-Institut für Kohlenforschung (MPI KoFo) / Max Planck Institute for Coal Research Germany (DE) New York Institute of Technology United States (USA) (US) Vanderbilt University United States (USA) (US) Columbia University United States (USA) (US)

How to cite

APA:

Gliemann, B., Petrovic, A.G., Zolnhofer, E., Dral, P.O., Hampel, F., Breitenbruch, G.,... Kivala, M. (2017). Configurationally Stable Chiral Dithia-Bridged Hetero[4]helicene Radical Cation: Electronic Structure and Absolute Configuration. Chemistry - An Asian Journal, 12(1), 31-35. https://doi.org/10.1002/asia.201601452

MLA:

Gliemann, Bettina, et al. "Configurationally Stable Chiral Dithia-Bridged Hetero[4]helicene Radical Cation: Electronic Structure and Absolute Configuration." Chemistry - An Asian Journal 12.1 (2017): 31-35.

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