Kaftan A, Klefer H, Haumann M, Laurin M, Wasserscheid P, Libuda J (2017)
Publication Status: Published
Publication Type: Journal article
Publication year: 2017
Publisher: ELSEVIER SCIENCE BV
Book Volume: 174
Pages Range: 245-250
DOI: 10.1016/j.seppur.2016.10.017
A novel gas purification material using a supported ionic liquid phase (SILP) has been investigated for removal of NH3 from ambient gas streams (1500 ppm NH3 in Ar). The SILP material is made of a thin film of an imidazolium based ionic liquid and a dissolved copper metal complex ([C(2)C(1)Im]Cl/CuC1(2)), which were dispersed in the pores of a silica 100 support. Diffuse reflection infrared Fourier transform spectroscopy (DRIFTS) was used to investigate the irreversible absorption from a 1500 ppm NH3 gas stream and to identify species formed upon physisorption and chemisorption of ammonia. Additionally, temperature-programmed DRIFTS combined with in situ mass spectrometry were used to evaluate the reversibility and regenerability of the system. (C) 2016 Elsevier B.V. All rights reserved.
APA:
Kaftan, A., Klefer, H., Haumann, M., Laurin, M., Wasserscheid, P., & Libuda, J. (2017). An operando DRIFTS-MS study of NH3 removal by supported ionic liquid phase (SILP) materials. Separation and Purification Technology, 174, 245-250. https://doi.org/10.1016/j.seppur.2016.10.017
MLA:
Kaftan, Andre, et al. "An operando DRIFTS-MS study of NH3 removal by supported ionic liquid phase (SILP) materials." Separation and Purification Technology 174 (2017): 245-250.
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