Tuning the Carbon Nanotube Selectivity: Optimizing Reduction Potentials and Distortion Angles in Perylenediimides
Münich PW, Schierl C, Dirian K, Volland M, Bauroth S, Wibmer L, Syrgiannis Z, Clark T, Prato M, Guldi DM (2018)
Publication Status: Published
Publication Type: Journal article
Publication year: 2018
Journal
Publisher: AMER CHEMICAL SOC
Book Volume: 140
Pages Range: 5427-5433
Journal Issue: 16
DOI: 10.1021/jacs.8b00452
Abstract
Different water-soluble perylenediimides (PDIs) have been used to individualize and stabilize single-walled carbon nanotubes (SWCNTs) in aqueous media. A key feature of the PDIs is that they can be substituted at the bay positions via the addition of two and/or four bromines. This enables control over structural and electronic PDI characteristics, which prompted us to conduct comparative assays with focus on SWCNTs' chirality and charge transfer. Electrochemical, microscopic, and spectroscopic experiments were used to investigate the SWCNT chiral selectivity of PDIs, on the one hand, and charge-transfer reactions between SWCNTs and PDIs, on the other hand.
Authors with CRIS profile
Peter Wilhelm Münich
Lehrstuhl für Physikalische Chemie I
Christoph Schierl
Lehrstuhl für Physikalische Chemie I
Konstantin Dirian
Lehrstuhl für Physikalische Chemie I
Michel Volland
Lehrstuhl für Physikalische Chemie I
Stefan Bauroth
Lehrstuhl für Physikalische Chemie I
Leonie Wibmer
Lehrstuhl für Organische Chemie II
Timothy Clark
Computer-Chemie-Centrum
Dirk Michael Guldi
Lehrstuhl für Physikalische Chemie I
Involved external institutions
Italy (IT)How to cite
APA:
Münich, P.W., Schierl, C., Dirian, K., Volland, M., Bauroth, S., Wibmer, L.,... Guldi, D.M. (2018). Tuning the Carbon Nanotube Selectivity: Optimizing Reduction Potentials and Distortion Angles in Perylenediimides. Journal of the American Chemical Society, 140(16), 5427-5433. https://doi.org/10.1021/jacs.8b00452
MLA:
Münich, Peter Wilhelm, et al. "Tuning the Carbon Nanotube Selectivity: Optimizing Reduction Potentials and Distortion Angles in Perylenediimides." Journal of the American Chemical Society 140.16 (2018): 5427-5433.
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