Synthesis of ZIF-11-Effect of water residues in the solvent onto the phase transition from ZIF-11 to ZIF-7-III

Reif B, Fabisch F, Hovestadt M, Hartmann M, Schwieger W (2017)

Publication Status: Published

Publication Type: Journal article

Publication year: 2017

Journal

Microporous and Mesoporous Materials Elsevier

Publisher: ELSEVIER SCIENCE BV

Book Volume: 243

Pages Range: 65-68

DOI: 10.1016/j.micromeso.2017.02.013

Abstract

The syntheses of MOFs and ZIFs are often accompanied by the formation of unwanted byproducts. Also for the ZIF-11 synthesis in N,N-Diethylformamide (DEF), phase impurities have been reported. In this systematic study, water residues in the reaction mixture could be identified as one major reason for the formation of the phase impurity ZIF-7-Ill within the ZIF-11 synthesis. The parameters 'crystallinity' and 'phase index' were introduced to quantify the phase transition. (C) 2017 Elsevier Inc. All rights reserved.

Authors with CRIS profile

Benjamin Reif Lehrstuhl für Chemische Reaktionstechnik (CRT) Florian Fabisch Lehrstuhl für Chemische Reaktionstechnik (CRT) Maximilian Hovestadt Interdisziplinäres Zentrum Erlangen Catalysis Resource Center (ECRC) Martin Hartmann Professur für Katalyse Wilhelm Schwieger Professur für Technische Chemie (Reaktionstechnik)

Additional Organisation(s)

Exzellenz-Cluster Engineering of Advanced Materials (EAM)

How to cite

APA:

Reif, B., Fabisch, F., Hovestadt, M., Hartmann, M., & Schwieger, W. (2017). Synthesis of ZIF-11-Effect of water residues in the solvent onto the phase transition from ZIF-11 to ZIF-7-III. Microporous and Mesoporous Materials, 243, 65-68. https://doi.org/10.1016/j.micromeso.2017.02.013

MLA:

Reif, Benjamin, et al. "Synthesis of ZIF-11-Effect of water residues in the solvent onto the phase transition from ZIF-11 to ZIF-7-III." Microporous and Mesoporous Materials 243 (2017): 65-68.

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