Supported ionic liquid phase (SILP) catalyzed hydroformylation of 1-butene in a gradient-free loop reactor

Haumann M, Jakuttis M, Werner S, Wasserscheid P (2009)

Publication Type: Journal article

Publication year: 2009

Journal

Journal of Catalysis Elsevier

Publisher: Elsevier

Book Volume: 263

Pages Range: 321--327

Volume: 263

Issue: 2

Journal Issue: 2

DOI: 10.1016/j.jcat.2009.02.024

Abstract

The supported ionic liquid phase (SILP) catalysis technology was applied to gas-phase hydroformylation of 1-butene using sulfoxantphos 1 modified rhodium complexes. Kinetic experiments were performed in a fixed bed reactor and compared to a gradient-free gas-phase loop reactor (Berty type). The influence of substrate concentration, temperature and syngas pressure was determined. Data from fixed bed and Berty reactor were found to be in good agreement with respect to activation energy and reaction order. Ex-situ NMR studies of fresh and used SILP catalysts confirmed that the ligand remained intact after prolonged time on stream.

Authors with CRIS profile

Marco Haumann Lehrstuhl für Chemische Reaktionstechnik Michael Jakuttis Lehrstuhl für Chemische Reaktionstechnik Sebastian Werner Graduiertenzentrum der FAU Peter Wasserscheid Lehrstuhl für Chemische Reaktionstechnik

Additional Organisation(s)

Exzellenz-Cluster Engineering of Advanced Materials

How to cite

APA:

Haumann, M., Jakuttis, M., Werner, S., & Wasserscheid, P. (2009). Supported ionic liquid phase (SILP) catalyzed hydroformylation of 1-butene in a gradient-free loop reactor. Journal of Catalysis, 263(2), 321--327. https://doi.org/10.1016/j.jcat.2009.02.024

MLA:

Haumann, Marco, et al. "Supported ionic liquid phase (SILP) catalyzed hydroformylation of 1-butene in a gradient-free loop reactor." Journal of Catalysis 263.2 (2009): 321--327.

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