Probing a gas/liquid acid-base reaction by X-ray photoelectron spectroscopy

Niedermaier I, Taccardi N, Wasserscheid P, Maier F, Steinrück HP (2013)

Publication Type: Journal article

Publication year: 2013

Journal

Angewandte Chemie International Edition Wiley

Original Authors: Niedermaier I., Taccardi N., Wasserscheid P., Maier F., Steinrück H.-P.

Publisher: Wiley-VCH Verlag

Book Volume: 52

Pages Range: 8904-8907

Journal Issue: 34

DOI: 10.1002/anie.201304115

Abstract

A mechanistic study: In a Brønsted acid/base reaction, gaseous triflic acid (OTfH) transfers its proton to the basic Cl anion of the ionic liquid [CCIm]Cl forming volatile HCl and the IL [CCIm][TfO]. This anion exchange reaction is monitored in the near-surface region quantitatively by X-ray photoelectron spectroscopy as a function of time (see picture; BE=binding energy). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Authors with CRIS profile

Inga Niedermaier Lehrstuhl für Physikalische Chemie II Nicola Taccardi Lehrstuhl für Chemische Reaktionstechnik (CRT) Peter Wasserscheid Lehrstuhl für Chemische Reaktionstechnik (CRT) Florian Maier Lehrstuhl für Physikalische Chemie II Hans-Peter Steinrück Lehrstuhl für Physikalische Chemie II

Additional Organisation(s)

Exzellenz-Cluster Engineering of Advanced Materials (EAM)

How to cite

APA:

Niedermaier, I., Taccardi, N., Wasserscheid, P., Maier, F., & Steinrück, H.-P. (2013). Probing a gas/liquid acid-base reaction by X-ray photoelectron spectroscopy. Angewandte Chemie International Edition, 52(34), 8904-8907. https://doi.org/10.1002/anie.201304115

MLA:

Niedermaier, Inga, et al. "Probing a gas/liquid acid-base reaction by X-ray photoelectron spectroscopy." Angewandte Chemie International Edition 52.34 (2013): 8904-8907.

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