A three-coordinate copper(II) amide from reductive cleavage of a nitrosamine

Melzer MM, Mossin S, Dai X, Bartell AM, Kapoor P, Meyer K, Warren TH (2010)

Publication Type: Journal article, Original article

Publication year: 2010

Journal

Angewandte Chemie International Edition Wiley

Original Authors: Melzer M.M., Mossin S., Dai X., Bartell A.M., Kapoor P., Meyer K., Warren T.H.

Publisher: Wiley-VCH Verlag

Book Volume: 49

Pages Range: 904-907

Journal Issue: 5

DOI: 10.1002/anie.200905171

Abstract

A NO-velty: A copper(1) β-diketiminate activates the nitrosamine Ph NNO to give a rare, three-coordinate copper(II) amide, [(Me NN)Cu-NPh ]. Reaction of this amide with NO returns Ph NNO as well as a mixed-valence species with NOfunctionalized β-diketiminate ligands (see scheme; Cu light blue, N dark blue, O red). Thus, both the cleavage and formation of R N-NO bonds may take place at a common copper center. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

Authors with CRIS profile

Karsten Meyer Lehrstuhl für Anorganische und Allgemeine Chemie

Involved external institutions

Georgetown University US United States (USA) (US)

How to cite

APA:

Melzer, M.M., Mossin, S., Dai, X., Bartell, A.M., Kapoor, P., Meyer, K., & Warren, T.H. (2010). A three-coordinate copper(II) amide from reductive cleavage of a nitrosamine. Angewandte Chemie International Edition, 49(5), 904-907. https://doi.org/10.1002/anie.200905171

MLA:

Melzer, Marie M., et al. "A three-coordinate copper(II) amide from reductive cleavage of a nitrosamine." Angewandte Chemie International Edition 49.5 (2010): 904-907.

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