A new diamantane functionalized tris(aryloxide) ligand system for small molecule activation chemistry at reactive uranium complexes

Lam OP, Heinemann FW, Meyer K (2010)

Publication Type: Journal article, Original article

Publication year: 2010

Journal

Comptes Rendus Chimie Elsevier Masson

Original Authors: Lam O.P., Heinemann F.W., Meyer K.

Publisher: Elsevier Masson

Book Volume: 13

Pages Range: 803-811

DOI: 10.1016/j.crci.2010.03.004

Abstract

The diamantane functionalized triazacyclononane ligand ( ArOH)tacn (L) has been synthesized and the reactivity of its U(III) metallated product [((ArO) tacn)U] (1) has been explored. Complex 1 promotes dichloromethane and azidotrimethylsilane activation to generate U(IV) complex [(( ArO)tacn)U(Cl)] (2) and U(V) complex [(( ArO)tacn) U(NTMS)] (3), respectively. Spectroscopic investigations of complexes 1, 2, and 3 will be discussed, along with molecular structures where possible. © 2010 Published by Elsevier Masson SAS on behalf of Académie des sciences.

Authors with CRIS profile

Frank Wilhelm Heinemann Lehrstuhl für Anorganische und Allgemeine Chemie Karsten Meyer Lehrstuhl für Anorganische und Allgemeine Chemie

How to cite

APA:

Lam, O.P., Heinemann, F.W., & Meyer, K. (2010). A new diamantane functionalized tris(aryloxide) ligand system for small molecule activation chemistry at reactive uranium complexes. Comptes Rendus Chimie, 13, 803-811. https://doi.org/10.1016/j.crci.2010.03.004

MLA:

Lam, Oanh P., Frank Wilhelm Heinemann, and Karsten Meyer. "A new diamantane functionalized tris(aryloxide) ligand system for small molecule activation chemistry at reactive uranium complexes." Comptes Rendus Chimie 13 (2010): 803-811.

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