Use of transient EPR spectroscopy of excited triplet state for the structural assignment of bisadducts of fullerene C60
Pasimeni L, Hirsch A, Lamparth I, Herzog A, Maggini M, Prato M, Scorrano G (1997)
Publication Type: Journal article, Original article
Publication year: 1997
Journal
Original Authors: Pasimeni L., Hirsch A., Lamparth I., Herzog A., Maggini M., Prato M., Corvaja C., Scorrano G.
Publisher: American Chemical Society
City/Town: Washington, DC, United States
Book Volume: 119
Pages Range: 12896-12901
Journal Issue: 52
DOI: 10.1021/ja9709583
Abstract
Transient EPR spectroscopy has been applied to measure the spectra of excited triplet states in two series of fullerene bisadducts. Eight different bisadducts of C with bis(ethoxycarbonyl)methylene and five bis-N-methylpyrrolidines have been analyzed. The D and E parameters of electron dipolar interaction and the populations of the zero field triplet sublevels, accounting for spin polarization, have been determined by spectrum simulation. They appear peculiar for each bisadduct. It is shown that triplet EPR technique represents a useful spectroscopic tool that allows structural assignments to bisadducts of C.
Authors with CRIS profile
Involved external institutions
University of Padua / Universita degli Studi di Padova
Italy (IT)
Università degli Studi di Trieste
Italy (IT)
Italy (IT)
Università degli Studi di Trieste
Italy (IT)
How to cite
APA:
Pasimeni, L., Hirsch, A., Lamparth, I., Herzog, A., Maggini, M., Prato, M., & Scorrano, G. (1997). Use of transient EPR spectroscopy of excited triplet state for the structural assignment of bisadducts of fullerene C60. Journal of the American Chemical Society, 119(52), 12896-12901. https://doi.org/10.1021/ja9709583
MLA:
Pasimeni, Luigi, et al. "Use of transient EPR spectroscopy of excited triplet state for the structural assignment of bisadducts of fullerene C60." Journal of the American Chemical Society 119.52 (1997): 12896-12901.
BibTeX: Download