Skiebe A, Hirsch A, Klos H, Gotschy B (1994)
Publication Type: Journal article, Original article
Publication year: 1994
Original Authors: Skiebe A., Hirsch A., Klos H., Gotschy B.
Publisher: Elsevier
Book Volume: 220
Pages Range: 138-140
URI: https://www.scopus.com/record/display.uri?eid=2-s2.0-0012900178&origin=inward
The treatment of C with the tertiary amine 1,8-diazabicyclo[5.4.0]undec-7-ene results in the formation of a diamagnetic zwitterion salt [DBU]C. This addition reaction was monitored in solution by UV/VIS/NIR and ESR spectroscopy. It is shown that in the first step a single electron transfer occurs leading to the C monoradical anion and the DBU radical cation. In a subsequent step [DBU]C is formed upon a radical recombination process. The represented results give evidence for the reaction mechanism of the nucleophilic amine additions to C proposed earlier. © 1994.
APA:
Skiebe, A., Hirsch, A., Klos, H., & Gotschy, B. (1994). [DBU]C60. Spin pairing in a fullerene salt. Chemical Physics Letters, 220, 138-140.
MLA:
Skiebe, Andreas, et al. "[DBU]C60. Spin pairing in a fullerene salt." Chemical Physics Letters 220 (1994): 138-140.
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