Selective synthesis of Co8S15 cluster in bowl-shaped template of the pentaaryl[60]fullerene ligand

Maruyama M, Imoto K, König M, Guldi DM, Ohkoshi SI, Nakamura E, Matsuo Y (2013)


Publication Type: Journal article, Original article

Publication year: 2013

Journal

Original Authors: Maruyama M., Imoto K., König M., Guldi D.M., Ohkoshi S.-I., Nakamura E., Matsuo Y.

Publisher: American Chemical Society

Book Volume: 135

Pages Range: 10914-10917

Journal Issue: 30

DOI: 10.1021/ja405045t

Abstract

A cobalt-sulfur cluster CoS with molecular formula of (CAr)-CoSBu-(CAr) (Ar = 4- BuCH) was selectively synthesized from a pentaaryl[60]fullerene cobalt trisulfide complex, (η-C Ar)CoS. The bowl-shaped steric templating fullerene ligand, as well as the metastable cobalt trisulfide moiety, played important roles in the exclusive cluster formation. X-ray crystallography, as well as electrochemical, time-resolved photophysical, and magnetic, measurements revealed a mixed-valence cluster with six cobalt(III) and two high-spin cobalt(II) centers showing reversible redox behavior and photoinduced charge separation. © 2013 American Chemical Society.

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APA:

Maruyama, M., Imoto, K., König, M., Guldi, D.M., Ohkoshi, S.-I., Nakamura, E., & Matsuo, Y. (2013). Selective synthesis of Co8S15 cluster in bowl-shaped template of the pentaaryl[60]fullerene ligand. Journal of the American Chemical Society, 135(30), 10914-10917. https://doi.org/10.1021/ja405045t

MLA:

Maruyama, Masashi, et al. "Selective synthesis of Co8S15 cluster in bowl-shaped template of the pentaaryl[60]fullerene ligand." Journal of the American Chemical Society 135.30 (2013): 10914-10917.

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