Massive conformational changes during thermally induced self-metalation of 2H-tetrakis-(3,5-di-tert-butyl)-phenylporphyrin on Cu(111)

Stark MW, Ditze S, Lepper M, Zhang L, Schlott H, Buchner F, Röckert M, Chen M, Lytken O, Steinrück HP, Marbach H (2014)

Publication Type: Journal article

Publication year: 2014

Journal

Chemical Communications Royal Society of Chemistry

Publisher: Royal Society of Chemistry

Book Volume: 50

Pages Range: 10225--10228

Volume: 50

Issue: 71

Journal Issue: 71

DOI: 10.1039/c4cc03708a

Abstract

Based on a combined scanning tunnelling microscopy and X-ray photoelectron spectroscopy study we present detailed insights into pronounced changes of long-range order and intramolecular conformation during the self-metalation of 2H-5,10,15,20-tetrakis-(3,5-di-tert-butyl)-phenylporphyrin (2HTTBPP) to CuTTBPP on Cu(111). Upon metalation, the porphyrin literally ``pops up'' from the surface, due to a drastically reduced molecule--substrate interaction.

Authors with CRIS profile

Michael Werner Stark Lehrstuhl für Physikalische Chemie II Stefanie Ditze Lehrstuhl für Physikalische Chemie II Michael Lepper Lehrstuhl für Physikalische Chemie II Liang Zhang Lehrstuhl für Physikalische Chemie II Hannah Schlott Interdisziplinäres Zentrum für Molekulare Materialien Michael Röckert Lehrstuhl für Physikalische Chemie II Min Chen Lehrstuhl für Physikalische Chemie II Ole Lytken Lehrstuhl für Physikalische Chemie II Hans-Peter Steinrück Lehrstuhl für Physikalische Chemie II Hubertus Marbach Lehrstuhl für Physikalische Chemie II

Additional Organisation(s)

Exzellenz-Cluster Engineering of Advanced Materials

How to cite

APA:

Stark, M.W., Ditze, S., Lepper, M., Zhang, L., Schlott, H., Buchner, F.,... Marbach, H. (2014). Massive conformational changes during thermally induced self-metalation of 2H-tetrakis-(3,5-di-tert-butyl)-phenylporphyrin on Cu(111). Chemical Communications, 50(71), 10225--10228. https://doi.org/10.1039/c4cc03708a

MLA:

Stark, Michael Werner, et al. "Massive conformational changes during thermally induced self-metalation of 2H-tetrakis-(3,5-di-tert-butyl)-phenylporphyrin on Cu(111)." Chemical Communications 50.71 (2014): 10225--10228.

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