Mäurer A, Breitinger D, Breiter R (1993)
Publication Language: English
Publication Status: Published
Publication Type: Journal article, Original article
Publication year: 1993
Book Volume: 48
Pages Range: 1187-1192
Journal Issue: 9
Fac-Li[Rh(SO)(OH)](OH) crystallizes in the rhombohedral space group R3-C , Z = 1, in trigonal setting a = 807.7(2), c = 1339.0(3) pm, V = 756.6(2)·10 pm, Z = 3. Rh is octahedrally coordinated by three facial S-bonded sulfite groups with Rh–S = 222.6(1) pm and three aqua ligands with Rh–O bonds Rh–O = 217.5(3) pm, elongated by a frans-influence. The average S–O bond length is 148.0(3) pm. All hydrogen atoms have been located. The OH ion is coordinated exclusively to Li. The anions are held together by Li cations in octahedral environment and by hydrogen bonds of medium strength. Alternatively, the structure can be considered to be built of packages of two oxygen nets and a metal layer, stacked in a sequence similar to that in the CdCl-structure. © 1993, Walter de Gruyter. All rights reserved.
APA:
Mäurer, A., Breitinger, D., & Breiter, R. (1993). The Crystal Structure of Lithium fac-Triaquatrisulfitorhodate(III)hydroxide, Li4[Rh(SO3)3(OH2)3](OH). Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences, 48(9), 1187-1192. https://doi.org/10.1515/znb-1993-0906
MLA:
Mäurer, Andreas, Dietrich Breitinger, and Roman Breiter. "The Crystal Structure of Lithium fac-Triaquatrisulfitorhodate(III)hydroxide, Li4[Rh(SO3)3(OH2)3](OH)." Zeitschrift für Naturforschung - Section B Journal of Chemical Sciences 48.9 (1993): 1187-1192.
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