Zenneck U, Hofmann M, Heinemann FW (2002)
Publication Type: Journal article
Publication year: 2002
Book Volume: 634-644
Pages Range: 357-362
DOI: 10.1016/S0022-328X(01)01211-6
The reaction of 1-trimethylstannyl-3,5-di(tert-butyl)-1,2,4-triphosphol with PPh3AuCl affords [(1,2,4-triphospholyl)Au(PPh3)] (5) in high yield. NMR spectra of 5 are indicative for a highly dynamic compound in solution. The molecular structure of 5 in the solid state is that of the dimer [(1,2,4-triphospholyl)Au(PPh3)]2. Its most striking feature is a remarkable range of different metal-triphospholyl ligand bonds which create a pronounced asymmetric core of the molecule. The central Au-Au distance of 3.14 Å indicates a weak interaction of the metal atoms. © 2002 Elsevier Science B.V. All rights reserved.
APA:
Zenneck, U., Hofmann, M., & Heinemann, F.W. (2002). A dimeric gold(I) triphospholyl complex. Journal of Organometallic Chemistry, 634-644, 357-362. https://doi.org/10.1016/S0022-328X(01)01211-6
MLA:
Zenneck, Ulrich, M. Hofmann, and Frank Wilhelm Heinemann. "A dimeric gold(I) triphospholyl complex." Journal of Organometallic Chemistry 634-644 (2002): 357-362.
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