Transition metal complexes bearing a 2,2-bis(3,5-dimethylpyrazol-1-yl) propionate ligand: One methyl more matters

Türkoglu G, Heinemann FW, Burzlaff N (2011)


Publication Type: Journal article, Original article

Publication year: 2011

Journal

Original Authors: Türkoglu G., Heinemann F.W., Burzlaff N.

Publisher: Royal Society of Chemistry

Book Volume: 40

Pages Range: 4678-4686

Journal Issue: 17

DOI: 10.1039/c1dt00022e

Abstract

The new N,N,O ligand 2,2-bis(3,5-dimethylpyrazol-1-yl)propionic acid (2,2-Hbdmpzp) (2) and its transition metal complexes [Mn(2,2-bdmpzp)(CO) ] (3), [Re(2,2-bdmpzp)(CO) ] (4), [Cu(2,2-bdmpzp) ] (5), and [Ru(2,2-bdmpzp)Cl(L)(PPh )] [L = PPh (6), N (7), CO (8a/b), SO (9a/b)] have been synthesized, characterized and compared to analogous complexes bearing a bis(3,5-dimethylpyrazol-1-yl)acetic acid. It was found that the additional methyl group has a remarkable influence on the stability and reactivity of transition metal complexes. © 2011 The Royal Society of Chemistry.

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How to cite

APA:

Türkoglu, G., Heinemann, F.W., & Burzlaff, N. (2011). Transition metal complexes bearing a 2,2-bis(3,5-dimethylpyrazol-1-yl) propionate ligand: One methyl more matters. Dalton Transactions, 40(17), 4678-4686. https://doi.org/10.1039/c1dt00022e

MLA:

Türkoglu, Gazi, Frank Wilhelm Heinemann, and Nicolai Burzlaff. "Transition metal complexes bearing a 2,2-bis(3,5-dimethylpyrazol-1-yl) propionate ligand: One methyl more matters." Dalton Transactions 40.17 (2011): 4678-4686.

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