Interfacial behavior of thin ionic liquid films on mica

Deyko A, Cremer T, Rietzler F, Perkin S, Crowhurst L, Welton T, Steinrück HP, Maier F (2013)

Publication Type: Journal article, Original article

Publication year: 2013

Journal

Original Authors: Deyko A., Cremer T., Rietzler F., Perkin S., Crowhurst L., Welton T., Steinrück H.-P., Maier F.

Publisher: American Chemical Society

Book Volume: 117

Pages Range: 5101-5111

Journal Issue: 10

DOI: 10.1021/jp3115397

Abstract

Ultrathin films of two imidazolium-based ionic liquids (ILs), [C CIm][TfN] (=1-methyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide) and [CCIm][Tf N] (=1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide) were deposited on mica surfaces by physical vapor deposition in ultrahigh vacuum. Using angle-resolved X-ray photoelectron spectroscopy (ARXPS), the initial wetting behavior, the growth characteristics, and the molecular arrangement of the ions at the interface were investigated. The measurements were performed on freshly air-cleaved mica surfaces with different carbon precoverages. ARXPS clearly reveals that the initial IL adsorption behavior strongly depends on the amount of preadsorbed carbon: On clean mica, 3D growth (complete dewetting) occurs, whereas on a fully carbon covered surface, initially a complete 2D wetting layer forms, followed by 3D growth. © 2013 American Chemical Society.

Authors with CRIS profile

Additional Organisation(s)

Involved external institutions

University of Oxford United Kingdom (GB) Imperial College London / The Imperial College of Science, Technology and Medicine United Kingdom (GB)

How to cite

APA:

Deyko, A., Cremer, T., Rietzler, F., Perkin, S., Crowhurst, L., Welton, T.,... Maier, F. (2013). Interfacial behavior of thin ionic liquid films on mica. Journal of Physical Chemistry C, 117(10), 5101-5111. https://doi.org/10.1021/jp3115397

MLA:

Deyko, Alexey, et al. "Interfacial behavior of thin ionic liquid films on mica." Journal of Physical Chemistry C 117.10 (2013): 5101-5111.

BibTeX: Download