Titanium isopropoxide complexes containing diamine bis-thiolato based [N2S2](2-) ligands; effect of steric bulk on coordination features
Shaban SY, Ramadan AEMM, Heinemann FW (2012)
Publication Status: Published
Publication Type: Journal article
Publication year: 2012
Journal
Publisher: ELSEVIER SCIENCE BV
Book Volume: 20
Pages Range: 135-137
DOI: 10.1016/j.inoche.2012.02.035
Abstract
Two dianionic amine bis(thiolato) ligands are introduced and their reactions with titanium tetra(iso-propoxide) studied; ligand N2H2S2 - H-2 (1) having NH donor groups leads exclusively to dinuclear [{Ti(N2H2S2)((OPr)-Pr-i)}(2)] (2) along with an oxidation product of the ligand (3) whereas ligand N2Me2S2 - H-2 (4) having an additional N-substituent leads exclusively to a mononuclear [Ti(N2Me2S2)((OPr)-Pr-i)(2))] (5) type complex. (C) 2012 Elsevier B.V. All rights reserved.
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APA:
Shaban, S.Y., Ramadan, A.E.-M.M., & Heinemann, F.W. (2012). Titanium isopropoxide complexes containing diamine bis-thiolato based [N2S2](2-) ligands; effect of steric bulk on coordination features. Inorganic Chemistry Communications, 20, 135-137. https://doi.org/10.1016/j.inoche.2012.02.035
MLA:
Shaban, Shaban Y., Abd El-Motaleb M. Ramadan, and Frank Wilhelm Heinemann. "Titanium isopropoxide complexes containing diamine bis-thiolato based [N2S2](2-) ligands; effect of steric bulk on coordination features." Inorganic Chemistry Communications 20 (2012): 135-137.
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