Phase Transition Behavior and Oriented Aggregation During Precipitation of In(OH)3 and InOOH Nanocrystals

Klaumünzer M, Mackovic M, Ferstl P, Voigt M, Spiecker E, Meyer B, Peukert W (2012)

Publication Language: English

Publication Type: Journal article, Original article

Publication year: 2012

Journal

Journal of Physical Chemistry C American Chemical Society

Publisher: American Chemical Society

Book Volume: 116

Pages Range: 24529--24537

Volume: 116

Issue: 46

Journal Issue: 46

DOI: 10.1021/jp305858n

Abstract

The phase transition behavior and oriented aggregation (OA) during colloidal synthesis of In(OH)3 nanocrystals in water are investigated by TEM, SEM, X-ray diffraction, and density functional theory (DFT) calculations. Besides the cubic In(OH)3 phase, also orthorhombic InOOH is formed in a precipitation route using indium acetate as the In3+ source. Well-developed nano- and microcuboids are observed that consist solely of In(OH)3. In contrast, the InOOH phase remains semicrystalline even for long reaction (refluxing) times. The irregular growth of the InOOH phase is explained by proton transfers from hydroxyl groups to oxygen ions within the InOOH lattice that lead to OH disorder and lattice strain. DFT calculations of the surface energies of ideal and water-saturated low-index InOOH and In(OH)3 surfaces predict that the In(OH)3 phase becomes energetically more favorable than InOOH above a critical crystallite size. This explains why InOOH is formed before the In(OH)3 phase, which is an unusual pathway for a hydrothermal process. Once InOOH has transformed to In(OH)3 by incorporation of water, the crystallites can grow without restriction due to the disappearance of OH-disorder-induced strain. Finally, for the In(OH)3 cuboids a three-step formation process is suggested: In the first step, one-dimensional OA under formation of nanorods occurs. In the second step, parallel bundles are formed from the nanorods. In the third step these bundles merge into cuboids by three-dimensional OA.

Authors with CRIS profile

Martin Klaumünzer Lehrstuhl für Feststoff- und Grenzflächenverfahrenstechnik Mirza Mackovic Lehrstuhl für Werkstoffwissenschaften (Mikro- und Nanostrukturforschung) Pascal Ferstl Professur für Experimentalphysik Michael Voigt Lehrstuhl für Feststoff- und Grenzflächenverfahrenstechnik Erdmann Spiecker Lehrstuhl für Werkstoffwissenschaften (Mikro- und Nanostrukturforschung) Bernd Meyer Professur für Computational Chemistry Wolfgang Peukert Lehrstuhl für Feststoff- und Grenzflächenverfahrenstechnik

Additional Organisation(s)

Lehrstuhl für Werkstoffwissenschaften (Mikro- und Nanostrukturforschung) Exzellenz-Cluster Engineering of Advanced Materials Interdisziplinäres Zentrum, Center for Nanoanalysis and Electron Microscopy (CENEM)

How to cite

APA:

Klaumünzer, M., Mackovic, M., Ferstl, P., Voigt, M., Spiecker, E., Meyer, B., & Peukert, W. (2012). Phase Transition Behavior and Oriented Aggregation During Precipitation of In(OH)3 and InOOH Nanocrystals. Journal of Physical Chemistry C, 116(46), 24529--24537. https://doi.org/10.1021/jp305858n

MLA:

Klaumünzer, Martin, et al. "Phase Transition Behavior and Oriented Aggregation During Precipitation of In(OH)3 and InOOH Nanocrystals." Journal of Physical Chemistry C 116.46 (2012): 24529--24537.

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