Screening of Supported Ionic Liquid Phase (SILP) catalysts for the very low temperature water--gas-shift reaction
Werner S, Szesni N, Bittermann A, Schneider M, Härter P, Haumann M, Wasserscheid P (2010)
Publication Type: Journal article
Publication year: 2010
Journal
Publisher: Elsevier
Book Volume: 377
Pages Range: 70--75
Volume: 377
Issue: 1-2
Journal Issue: 1-2
DOI: 10.1016/j.apcata.2010.01.019
Abstract
Screening of transition metal complexes typically involves elaborative experiments in batch reactors in organic solvents under non-steady-state conditions. In contrast, screening of immobilized catalysts in a fixed-bed continuous gas-phase reactor enables highly efficient and precise investigations on activity and stability under steady-state. In this work we present a technique to immobilize numerous homogeneous transition metal complexes (Ru, Ir, Os, Fe, Cu, Mo, Pd Re, Rh) in the ionic liquid [BMMIM][OTf] on the highly porous support Silica 100 using the Supported Ionic Liquid Phase (SILP) technology. All prepared SILP catalysts were investigated in the water--gas shift reaction (WGSR) in a continuously operated fixed-bed reactor at temperatures between 120 and 160~°C and ambient pressure. Best activities and stabilities were found for ruthenium-based systems.
Authors with CRIS profile
Sebastian Werner
Graduiertenzentrum der FAU
Martin Schneider
Lehrstuhl für Chemische Reaktionstechnik
Marco Haumann
Lehrstuhl für Chemische Reaktionstechnik
Peter Wasserscheid
Lehrstuhl für Chemische Reaktionstechnik
Additional Organisation(s)
Involved external institutions
Germany (DE)How to cite
APA:
Werner, S., Szesni, N., Bittermann, A., Schneider, M., Härter, P., Haumann, M., & Wasserscheid, P. (2010). Screening of Supported Ionic Liquid Phase (SILP) catalysts for the very low temperature water--gas-shift reaction. Applied Catalysis A-General, 377(1-2), 70--75. https://doi.org/10.1016/j.apcata.2010.01.019
MLA:
Werner, Sebastian, et al. "Screening of Supported Ionic Liquid Phase (SILP) catalysts for the very low temperature water--gas-shift reaction." Applied Catalysis A-General 377.1-2 (2010): 70--75.
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