Ellermann J, Sutter J, Schelle C, Knoch F, Moll M (1993)
Publication Status: Published
Publication Type: Journal article, Original article
Publication year: 1993
Original Authors: Ellermann J, Sutter J, Schelle C, Knoch FA, Moll M
Publisher: Wiley-VCH Verlag
Book Volume: 619
Pages Range: 2006-2014
Journal Issue: 12
When anhyd. MCl2 (M = Ni, Pd) is treated with LiN(PPh2)2 (1) in the molar ratio 1:2 in boiling toluene for 60 h the new spirocyclic metallaphosphazenes I (M = Ni, Pd) are obtained by oxidative scrambling of the P-N-P anion in 1. N(PPh2)3, the elemental metals, and LiCl are also formed. The compds. I are characterized by IR, Raman, 31P{1H} NMR, 1H-NMR, 13C{H} NMR, and FD mass spectra. The x-ray crystal structures of I·CH2Cl2 (M = Ni) and I·0.597CH2Cl2 (M = Pd) show that the metals in I occupy a mid-position between tetrahedral and square planar coordination. Both rings in I show a torsion angle of nearly 45° at the spirocyclic metal center. [on SciFinder(R)]
APA:
Ellermann, J., Sutter, J., Schelle, C., Knoch, F., & Moll, M. (1993). Chemistry of polyfunctional molecules. 111. Synthesis and structure of novel spirocyclic nickel(II) and palladium(II) complexes with the phosphazene anion [Ph2P-N-P(Ph2)-N-PPh2]. Zeitschrift für Anorganische und Allgemeine Chemie, 619(12), 2006-2014. https://doi.org/10.1002/zaac.19936191208
MLA:
Ellermann, J., et al. "Chemistry of polyfunctional molecules. 111. Synthesis and structure of novel spirocyclic nickel(II) and palladium(II) complexes with the phosphazene anion [Ph2P-N-P(Ph2)-N-PPh2]." Zeitschrift für Anorganische und Allgemeine Chemie 619.12 (1993): 2006-2014.
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