Home Publications Research Grants Inventions & Patents Awards Additional Research Activities Faculties & Institutions Research Areas

Weak M-H center dot center dot center dot H-C and M-Cl center dot center dot center dot H-C interactions in orthometalated iridium and rhodium complexes

Huang LY, Aulwurm U, Heinemann FW, Knock F, Kisch H (1998)

---

Publication Status: Published

Publication Type: Journal article

Publication year: 1998

Journal

Publisher: WILEY-V C H VERLAG GMBH

Book Volume: 4

Pages Range: 1641-1646

Journal Issue: 9

Abstract

Four different types of intramolecular MX ... C interactions have been observed in a series of five, structurally very similar, orthometalated iridium(III) and rhodium(III) complexes. For X=H and M=Ir or Rh, two-center or three-center interactions with MH ... HC distances of 1.80 - 1.83 (M = Ir) or 2.00 -2.20 Angstrom (M = Rh) were observed. For X=Cl the MCl ... HC distances of the three-center arrangement (M = Ir) were in the range of 2.38-2.60 Angstrom, while values of 2.41-2.89 Angstrom were found for the four-center geometry (M = Rh), These weak interactions open new perspectives for the mechanism of cyclometalations.

Authors with CRIS profile

How to cite

APA:

Huang, L.Y., Aulwurm, U., Heinemann, F.W., Knock, F., & Kisch, H. (1998). Weak M-H center dot center dot center dot H-C and M-Cl center dot center dot center dot H-C interactions in orthometalated iridium and rhodium complexes. Chemistry - A European Journal, 4(9), 1641-1646.

MLA:

Huang, L. Y., et al. "Weak M-H center dot center dot center dot H-C and M-Cl center dot center dot center dot H-C interactions in orthometalated iridium and rhodium complexes." Chemistry - A European Journal 4.9 (1998): 1641-1646.

BibTeX: Download