Schatz J, Schildbach F, Lentz A, Rastätter S, Schilling J, Dormann JM, Ruoff A, Debaerdemaeker T (2000)
Publication Type: Journal article, Original article
Publication year: 2000
Original Authors: Schatz J., Schildbach F., Lentz A., Rastätter S., Schilling J., Dormann J., Ruoff A., Debaerdemaeker T.
Publisher: Verlag der Zeitschrift Fuer Naturforschung
Book Volume: 55
Pages Range: 213-221
Journal Issue: 2
URI: https://www.scopus.com/record/display.uri?eid=2-s2.0-0039030927&origin=inward
The inclusion complexes formed from carbon disulfide and p-tert-butylcalix[4]arene (1·CS) or p-tert-butylcalix[6]arene (2·CS) were investigated by X-ray crystal structure analysis, infrared (IR) and Raman spectroscopy. The complex 1·CS crystallises in the space group P4/n, 2·CS in the space group P2/n. In case of p-tert-butylcalix[4]arene as host the carbon disulfide molecule is included in the cavity. In the crystal structure of p-tert-butylcalix[6]arene clathrate, self-complexation of one tert-butyl group in the cavity of another calix[6]arene can be observed. Due to inclusion, the symmetry of CS is lowered both in the p-tert-butylcalix[4]arene and p-tert-butylcalix[6]arene case causing significant shifts in the fully assigned infrared and Raman spectra.
APA:
Schatz, J., Schildbach, F., Lentz, A., Rastätter, S., Schilling, J., Dormann, J.M.,... Debaerdemaeker, T. (2000). The inclusion of carbon disulfide in p-tert-butylcalix[4]-and [6]arene - A combined crystallographic and vibrational spectroscopic study. Zeitschrift für Naturforschung Section B-A Journal of Chemical Sciences, 55(2), 213-221.
MLA:
Schatz, Jürgen, et al. "The inclusion of carbon disulfide in p-tert-butylcalix[4]-and [6]arene - A combined crystallographic and vibrational spectroscopic study." Zeitschrift für Naturforschung Section B-A Journal of Chemical Sciences 55.2 (2000): 213-221.
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