Fundamental Insights into the Degradation and Stabilization of Thin Layer Black Phosphorus
Abellan G, Wild S, Lloret V, Scheuschner N, Gillen R, Mundloch U, Maultzsch J, Varela M, Hauke F, Hirsch A (2017)
Publication Status: Published
Publication Type: Journal article
Publication year: 2017
Journal
Publisher: AMER CHEMICAL SOC
Book Volume: 139
Pages Range: 10432-10440
Journal Issue: 30
DOI: 10.1021/jacs.7b04971
Abstract
Herein, we have developed a systematic study on the oxidation and passivation of mechanically exfoliated black phosphorus (BP). We analyzed the strong anisotropic behavior of BP by scanning Raman microscopy providing an accurate method for monitoring the oxidation of BP-via statistical Raman spectroscopy. Furthermore, different factors influencing the environmental instability of the BP, i.e., thickness, lateral dimensions or visible light illumination, have been investigated in detail. Finally, we discovered that the degradation of few-layer BP flakes of <10 nm can be suppressed for months by using ionic liquids, paving the way for the development of BP-based technologies.
Authors with CRIS profile
Stefan Wild
Lehrstuhl für Organische Chemie II
Roland Gillen
Lehrstuhl für Experimentalphysik
Udo Mundloch
Lehrstuhl für Organische Chemie II
Janina Maultzsch
Lehrstuhl für Experimentalphysik
Frank Hauke
Lehrstuhl für Organische Chemie II
Andreas Hirsch
Lehrstuhl für Organische Chemie II
Involved external institutions
Germany (DE)
Spain (ES)How to cite
APA:
Abellan, G., Wild, S., Lloret, V., Scheuschner, N., Gillen, R., Mundloch, U.,... Hirsch, A. (2017). Fundamental Insights into the Degradation and Stabilization of Thin Layer Black Phosphorus. Journal of the American Chemical Society, 139(30), 10432-10440. https://dx.doi.org/10.1021/jacs.7b04971
MLA:
Abellan, Gonzalo, et al. "Fundamental Insights into the Degradation and Stabilization of Thin Layer Black Phosphorus." Journal of the American Chemical Society 139.30 (2017): 10432-10440.
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