Kohler F, Roth D, Kuhlmann E, Wasserscheid P, Haumann M (2010)
Publication Type: Journal article
Publication year: 2010
Publisher: Royal Society of Chemistry
Book Volume: 12
Pages Range: 979
Volume: 12
Issue: 6
Journal Issue: 6
DOI: 10.1039/C004883f
Supported ionic liquid phase (SILP) materials have been developed for a continuous gas cleaning process. The technology is exemplified for the desulfurisation of a model gas stream consisting of 500 ppmwtn-butyl mercaptan in n-heptane vapour to levels of mercaptan below 5 ppmwt. By varying the ionic liquid structure, acidity and loading, [C12MIM]Cl/SnCl2 (XSnCl2 = 0.50) on alumina in an ionic liquid loading of 20 vol{\%} of the support's pore volume was identified as a particularly suitable gas sorption system. Breakthrough experiments demonstrate desulfurisation performance of up to 130 h time-on-stream, and the suitability of the system for loading/unloading cycles in a pressure and temperature swing operation mode.
APA:
Kohler, F., Roth, D., Kuhlmann, E., Wasserscheid, P., & Haumann, M. (2010). Continuous gas-phase desulfurisation using supported ionic liquid phase (SILP) materials. Green Chemistry, 12(6), 979. https://dx.doi.org/10.1039/C004883f
MLA:
Kohler, Florian, et al. "Continuous gas-phase desulfurisation using supported ionic liquid phase (SILP) materials." Green Chemistry 12.6 (2010): 979.
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