Spontaneous Assembly of a Schiff Base Tetramacrocycle.

Schmidt S, Bauer W, Heinemann FW, Lanig H, Grohmann A (2000)


Publication Language: English

Publication Status: Published

Publication Type: Journal article, Original article

Publication year: 2000

Journal

Book Volume: 39

Pages Range: 913-916

Journal Issue: 5

DOI: 10.1002/(SICI)1521-3773(20000303)39:5%3C913::AID-ANIE913%3E3.0.CO;2-Y

Abstract

A hexaprotonated “supermacrocycle” of Schiff base macrocycles forms as the only product (>90 % yield) in a nine‐component condensation of the tetrapodal pentaamine 1 with the dialdehyde 2 in the presence of protons (see scheme). The molecule is chiral, and enantiomers in the racemic mixture interconvert by inversion of the large macrocyclic ring, as documented by 1H ROESY/EXSY NMR spectroscopy.

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How to cite

APA:

Schmidt, S., Bauer, W., Heinemann, F.W., Lanig, H., & Grohmann, A. (2000). Spontaneous Assembly of a Schiff Base Tetramacrocycle. Angewandte Chemie International Edition, 39(5), 913-916. https://dx.doi.org/10.1002/(SICI)1521-3773(20000303)39:5%3C913::AID-ANIE913%3E3.0.CO;2-Y

MLA:

Schmidt, Stefan, et al. "Spontaneous Assembly of a Schiff Base Tetramacrocycle." Angewandte Chemie International Edition 39.5 (2000): 913-916.

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