Increasing the Equilibrium Yield of Oxidative Dehydrogenation with CO2 by Secondary Reactions

Müller K, Baumgärtner A, Mokrushina L, Arlt W (2014)

Publication Status: Published

Publication Type: Journal article

Publication year: 2014

Journal

Chemical Engineering & Technology Wiley-VCH Verlag

Publisher: Wiley-VCH Verlag

Book Volume: 37

Pages Range: 1261-1264

Journal Issue: 7

DOI: 10.1002/ceat.201300823

Abstract

Oxidative dehydrogenation with carbon dioxide as an oxidant at low temperatures is strongly limited by its thermodynamic equilibrium. It is be shown that the equilibrium yield of the desired olefin can significantly be increased utilizing side reactions. This does not necessarily require the addition of another reactant, since this reactant can be formed in situ from the starting alkane. This effect allows for a decrease of the reaction temperature as well as the overall heat demand of the reaction. As a consequence, the exergy demand of the reaction system is reduced substantially.

Authors with CRIS profile

Karsten Müller Lehrstuhl für Thermische Verfahrenstechnik Andrea Fischer Lehrstuhl für Thermische Verfahrenstechnik Liudmila Mokrushina Lehrstuhl für Thermische Verfahrenstechnik Wolfgang Arlt Lehrstuhl für Thermische Verfahrenstechnik

How to cite

APA:

Müller, K., Baumgärtner, A., Mokrushina, L., & Arlt, W. (2014). Increasing the Equilibrium Yield of Oxidative Dehydrogenation with CO2 by Secondary Reactions. Chemical Engineering & Technology, 37(7), 1261-1264. https://doi.org/10.1002/ceat.201300823

MLA:

Müller, Karsten, et al. "Increasing the Equilibrium Yield of Oxidative Dehydrogenation with CO2 by Secondary Reactions." Chemical Engineering & Technology 37.7 (2014): 1261-1264.

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