Synthesis and characterization of iron trisphenolate complexes with hydrogen-bonding cavities

Adelhardt M, Chalkley M, Heinemann FW, Sutter J, Scheurer A, Meyer K (2014)

Publication Type: Journal article, Letter

Publication year: 2014

Journal

Original Authors: Adelhardt M., Chalkley M.J., Heinemann F.W., Sutter J., Scheurer A., Meyer K.

Publisher: American Chemical Society

Book Volume: 53

Pages Range: 2763-2765

Journal Issue: 6

URI: http://pubs.acs.org/doi/abs/10.1021/ic5002286

DOI: 10.1021/ic5002286

Abstract

A new family of C-symmetric ligands, featuring phenolate donors and a secondary coordination sphere, have been synthesized. We report the synthesis and subsequent coordination chemistry of these new tripodal N-anchored tris(phenolate) chelates, [tris(5-tert-butyl-3-N-carboxamide-2-hydroxybenzyl) amines] (HSalAmi), to iron(II), iron(III), and zinc(II). These electron-rich complexes have intramolecular hydrogen bonds, and therefore the potential to stabilize biologically relevant substrates in small-molecule activation chemistry. © 2014 American Chemical Society.

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How to cite

APA:

Adelhardt, M., Chalkley, M., Heinemann, F.W., Sutter, J., Scheurer, A., & Meyer, K. (2014). Synthesis and characterization of iron trisphenolate complexes with hydrogen-bonding cavities. Inorganic Chemistry, 53(6), 2763-2765. https://dx.doi.org/10.1021/ic5002286

MLA:

Adelhardt, Mario, et al. "Synthesis and characterization of iron trisphenolate complexes with hydrogen-bonding cavities." Inorganic Chemistry 53.6 (2014): 2763-2765.

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