Characterization of an iron-ruthenium interaction in a ferrocene diamide complex
Green AG, Kiesz MD, Oria JV, Elliott AG, Buechler AK, Hohenberger J, Meyer K, Zink JI, Diaconescu PL (2013)
Publication Type: Journal article, Original article
Publication year: 2013
Journal
Original Authors: Green A.G., Kiesz M.D., Oria J.V., Elliott A.G., Buechler A.K., Hohenberger J., Meyer K., Zink J.I., Diaconescu P.L.
Publisher: American Chemical Society
Book Volume: 52
Pages Range: 5603-5610
Journal Issue: 9
DOI: 10.1021/ic400773s
Abstract
Reaction of [fc(NH)]RuCl(PPh ) (fc = 1,1′-ferrocenylene) with 2 equiv of KOBu led to the formation of a diamido ruthenium complex, [fc(NH)]Ru(PPh), whose solid-state molecular structure revealed a short Fe-Ru distance. A metal-to-metal charge transfer band was observed in the electronic absorption spectrum of [fc(NH) ]Ru(PPh). The Fe-Ru interaction was characterized by resonance Raman spectroscopy for the first time and also by H NMR, UV-vis, NIR, Mössbauer spectroscopy, and X-ray crystallography. Density functional theory (DFT) calculations including natural bond order analysis, Bader's atom in molecules method, and time-dependent DFT (TDDFT) provided further support that the iron-ruthenium bond is a weak donor-acceptor interaction with iron acting as the Lewis base. © 2013 American Chemical Society.
Authors with CRIS profile
Johannes Hohenberger
Lehrstuhl für Anorganische und Allgemeine Chemie
Karsten Meyer
Lehrstuhl für Anorganische und Allgemeine Chemie
Involved external institutions
United States (USA) (US)How to cite
APA:
Green, A.G., Kiesz, M.D., Oria, J.V., Elliott, A.G., Buechler, A.K., Hohenberger, J.,... Diaconescu, P.L. (2013). Characterization of an iron-ruthenium interaction in a ferrocene diamide complex. Inorganic Chemistry, 52(9), 5603-5610. https://dx.doi.org/10.1021/ic400773s
MLA:
Green, Aaron G., et al. "Characterization of an iron-ruthenium interaction in a ferrocene diamide complex." Inorganic Chemistry 52.9 (2013): 5603-5610.
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