Tetraalkylphosphonium decavanadates: Synthesis, structures, and solution properties

Mal SS, Tröppner O, Ivanovic-Burmazovic I, Burger P (2013)


Publication Type: Journal article, Original article

Publication year: 2013

Journal

Original Authors: Mal S., Tröppner O., Ivanovic̈-Burmazovic̈ I., Burger P.

Publisher: Wiley-VCH Verlag

Book Volume: null

Pages Range: 1960-1967

Journal Issue: null

DOI: 10.1002/ejic.201201447

Abstract

A novel intercluster compound, [(n-CH) P][HVO] (IL01-V), constructed from the tetrabutylphosphonium cation and decavanadate, has been synthesized and unequivocally characterized by elemental analysis, FTIR spectroscopy, mass spectrometry, X-ray crystallography, and solution H, C, P{H}, and V NMR spectroscopy. Compound IL01-V was formed by ionic interaction between the phosphonium cation and the decavanadate anion. Cryospray high-resolution mass spectrometry revealed the [HV O] cluster remains intact in solution. Three further phosphonium polyoxovanadates were synthesized and characterized by the same techniques as used for IL01-V. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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How to cite

APA:

Mal, S.S., Tröppner, O., Ivanovic-Burmazovic, I., & Burger, P. (2013). Tetraalkylphosphonium decavanadates: Synthesis, structures, and solution properties. European Journal of Inorganic Chemistry, null(null), 1960-1967. https://dx.doi.org/10.1002/ejic.201201447

MLA:

Mal, Sib Sankar, et al. "Tetraalkylphosphonium decavanadates: Synthesis, structures, and solution properties." European Journal of Inorganic Chemistry null.null (2013): 1960-1967.

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