Kratzer A, Englert J, Lungerich D, Heinemann FW, Jux N, Hirsch A (2014)
Publication Status: Published
Publication Type: Journal article
Publication year: 2014
Book Volume: 173
Pages Range: 297-310
DOI: 10.1039/c4fd00069b
The synthesis of a new hexa-peri-hexabenzocoronene (HBC)-fullerene dyad was accomplished involving a covalent linkage between both the planar and the spherical conjugated π-system of the two chromophores. We also present the first X-ray single crystal structure of a HBC-fullerene conjugate. A very short HBC-fullerene distance of 3.2 Å is observed. For the synthesis of this molecule, a new versatile applicable template, namely, a mono-functionalized hexa-peri-hexabenzocoronene was attached to a fullerene. Absorption and fluorescence spectroscopy, as well as quantum yield measurements of , indicated close electronic communication between the two subunits, which is promising for possible applications in molecular electronics.
APA:
Kratzer, A., Englert, J., Lungerich, D., Heinemann, F.W., Jux, N., & Hirsch, A. (2014). Synthesis and first X-ray structure of a hexa-peri-hexabenzocoronene-fullerene-dyad: a model for an inter-carbon-allotrope hybrid. Faraday Discussions, 173, 297-310. https://dx.doi.org/10.1039/c4fd00069b
MLA:
Kratzer, Andreas, et al. "Synthesis and first X-ray structure of a hexa-peri-hexabenzocoronene-fullerene-dyad: a model for an inter-carbon-allotrope hybrid." Faraday Discussions 173 (2014): 297-310.
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