Journal article


Synthesis of ZIF-11-Effect of water residues in the solvent onto the phase transition from ZIF-11 to ZIF-7-III


Publication Details
Author(s): Reif B, Fabisch F, Hovestadt M, Hartmann M, Schwieger W
Publisher: ELSEVIER SCIENCE BV
Publication year: 2017
Volume: 243
Pages range: 65-68
ISSN: 1387-1811

Abstract

The syntheses of MOFs and ZIFs are often accompanied by the formation of unwanted byproducts. Also for the ZIF-11 synthesis in N,N-Diethylformamide (DEF), phase impurities have been reported. In this systematic study, water residues in the reaction mixture could be identified as one major reason for the formation of the phase impurity ZIF-7-Ill within the ZIF-11 synthesis. The parameters 'crystallinity' and 'phase index' were introduced to quantify the phase transition. (C) 2017 Elsevier Inc. All rights reserved.



How to cite
APA: Reif, B., Fabisch, F., Hovestadt, M., Hartmann, M., & Schwieger, W. (2017). Synthesis of ZIF-11-Effect of water residues in the solvent onto the phase transition from ZIF-11 to ZIF-7-III. Microporous and Mesoporous Materials, 243, 65-68. https://dx.doi.org/10.1016/j.micromeso.2017.02.013

MLA: Reif, Benjamin, et al. "Synthesis of ZIF-11-Effect of water residues in the solvent onto the phase transition from ZIF-11 to ZIF-7-III." Microporous and Mesoporous Materials 243 (2017): 65-68.

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