In situ structural analysis of calcium aluminosilicate glasses under high pressure

Muniz RF, de Ligny D, Martinet C, Sandrini M, Medina AN, Rohling JH, Baesso ML, Lima SM, Andrade LHC, Guyot Y (2016)

Publication Status: Published

Publication Type: Journal article

Publication year: 2016

Journal

Journal of Physics: Condensed Matter Institute of Physics: Hybrid Open Access

Publisher: Institute of Physics: Hybrid Open Access

Book Volume: 28

Journal Issue: 31

DOI: 10.1088/0953-8984/28/31/315402

Abstract

In situ micro-Raman spectroscopy was used to investigate the structural evolution of OH--free calcium aluminosilicate glasses, under high pressure and at room temperature. Evaluation was made of the role of the SiO2 concentration in percalcic join systems, for Al/(Al + Si) in the approximate range from 0.9 to 0.2. Under high pressure, the intensity of the main band related to the bending mode of bridging oxygen (nu(B)[T-O-T], where T = Si or Al) decreased gradually, suggesting that the bonds were severely altered or even destroyed. In Si-rich glasses, compression induced a transformation of Qn species to Qn-1. In the case of Al-rich glass, the Al in the smallest Qn units evolved from tetrahedral to higher-coordinated Al ([5] Al and [6] Al). Permanent structural changes were observed in samples recovered from the highest pressure of around 15 GPa and, particularly for Si-rich samples, the recovered structure showed an increase of three-membered rings in the Si/Al tetrahedral network.

Authors with CRIS profile

Dominique de Ligny Professur für Werkstoffwissenschaften (Glas und Keramik)

Involved external institutions

Université Claude Bernard Lyon 1 (UCB) FR France (FR) Universidade Estadual de Mato Grosso do Sul (UEMS) / State University of Mato Grosso do Sul BR Brazil (BR) Universidade Estadual de Maringá (UEM) / Maringá State University BR Brazil (BR)

How to cite

APA:

Muniz, R.F., de Ligny, D., Martinet, C., Sandrini, M., Medina, A.N., Rohling, J.H.,... Guyot, Y. (2016). In situ structural analysis of calcium aluminosilicate glasses under high pressure. Journal of Physics: Condensed Matter, 28(31). https://dx.doi.org/10.1088/0953-8984/28/31/315402

MLA:

Muniz, R. F., et al. "In situ structural analysis of calcium aluminosilicate glasses under high pressure." Journal of Physics: Condensed Matter 28.31 (2016).

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