Clark T (1994)
Publication Status: Published
Publication Type: Journal article
Publication year: 1994
Publisher: Verlag der Zeitschrift Fuer Naturforschung
Book Volume: 49
Pages Range: 1737-1742
Journal Issue: 12
The oxidation of E-1,2-di-tert-butyl-1,2-dimesityl disilene (1) in benzene by gaseous dioxygen to give 2 and 3 has been studied at various temperatures and with rapid or slow addition of oxygen. The effect of various additives (amines, phosphines, THF) on the product distribution was also investigated. Ab initio MO calculations were carried out on the oxidation of H2Si=SiH2 with triplet oxygen. These led to a proposed reaction mechanism for the oxidation of 1, in which the initial intermediate is a disileneperoxy biradical 6', which can close to give 2 or react with another molecule of disilene to give ultimately 3.
APA:
Clark, T. (1994). OXIDATION OF DISILENES - EXPERIMENTAL AND THEORETICAL-STUDIES. Zeitschrift für Naturforschung Section B-A Journal of Chemical Sciences, 49(12), 1737-1742. https://dx.doi.org/10.1515/znb-1994-1219
MLA:
Clark, Timothy. "OXIDATION OF DISILENES - EXPERIMENTAL AND THEORETICAL-STUDIES." Zeitschrift für Naturforschung Section B-A Journal of Chemical Sciences 49.12 (1994): 1737-1742.
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