Molecular docking sites designed for the generation of highly crystalline covalent organic frameworks

Ascherl L, Sick T, Margraf J, Lapidus SH, Calik M, Hettstedt C, Karaghiosoff K, Doeblinger M, Clark T, Chapman KW, Auras F, Bein T (2016)

Publication Status: Published

Publication Type: Journal article

Publication year: 2016

Journal

Nature Chemistry Nature Publishing Group

Publisher: Nature Publishing Group

Book Volume: 8

Pages Range: 310-316

Journal Issue: 4

DOI: 10.1038/NCHEM.2444

Abstract

Covalent organic frameworks (COFs) formed by connecting multidentate organic building blocks through covalent bonds provide a platform for designing multifunctional porous materials with atomic precision. As they are promising materials for applications in optoelectronics, they would benefit from a maximum degree of long-range order within the framework, which has remained a major challenge. We have developed a synthetic concept to allow consecutive COF sheets to lock in position during crystal growth, and thus minimize the occurrence of stacking faults and dislocations. Hereby, the three-dimensional conformation of propeller-shaped molecular building units was used to generate well-defined periodic docking sites, which guided the attachment of successive building blocks that, in turn, promoted long-range order during COF formation. This approach enables us to achieve a very high crystallinity for a series of COFs that comprise tri- and tetradentate central building blocks. We expect this strategy to be transferable to a broad range of customized COFs.

Authors with CRIS profile

Johannes Margraf Lehrstuhl für Theoretische Chemie Timothy Clark Computer-Chemie-Centrum

Involved external institutions

Ludwig-Maximilians-Universität (LMU) DE Germany (DE) Argonne National Laboratory US United States (USA) (US)

How to cite

APA:

Ascherl, L., Sick, T., Margraf, J., Lapidus, S.H., Calik, M., Hettstedt, C.,... Bein, T. (2016). Molecular docking sites designed for the generation of highly crystalline covalent organic frameworks. Nature Chemistry, 8(4), 310-316. https://doi.org/10.1038/NCHEM.2444

MLA:

Ascherl, Laura, et al. "Molecular docking sites designed for the generation of highly crystalline covalent organic frameworks." Nature Chemistry 8.4 (2016): 310-316.

BibTeX: Download