Journal article


Evidence for associative ligand exchange processes on solvated lithium cations


Publication Details
Author(s): Puchta R, Galle M, van Eikema Hommes N, Pasgreta E, van Eldik R
Publisher: American Chemical Society
Publication year: 2004
Volume: 43
Journal issue: 26
Pages range: 8227-8229
ISSN: 0020-1669

Abstract

The ligand exchange mechanism of solvated lithium cations has been studied using DFT calculations (RB3LYP/6-311+G**). The water exchange mechanism on [Li(H2O)(4)](+) was found to be limiting associative (A) involving a five-coordinate intermediate, whereas ammonia exchange on [Li(NH3)(4)](+) was found to follow an associative interchange (I-a) mechanism. The suggested mechanisms are discussed in reference to available experimental and theoretical data.



How to cite
APA: Puchta, R., Galle, M., van Eikema Hommes, N., Pasgreta, E., & van Eldik, R. (2004). Evidence for associative ligand exchange processes on solvated lithium cations. Inorganic Chemistry, 43(26), 8227-8229. https://dx.doi.org/10.1021/ic0487979

MLA: Puchta, Ralph, et al. "Evidence for associative ligand exchange processes on solvated lithium cations." Inorganic Chemistry 43.26 (2004): 8227-8229.

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