Journal article


Bicyclic diironcryptates with mobile guest cations: A new class of solid ionic conductors


Publication Details
Author(s): Puchta R, Roling B, Scheurer A, Weiskopf V, Hampel F, van Eikema Hommes N, Hummel HU
Publisher: Elsevier
Publication year: 2008
Volume: 179
Journal issue: 13-14
Pages range: 489-494
ISSN: 0167-2738

Abstract

Polycrystalline bicyclic diironcryptates with different mobile guest cations were synthesized and characterized by XRD analysis, IR spectroscopy, FAB-mass spectroscopy, elemental analysis, electrical conductivity spectroscopy and ion exchange experiments. We find strong indication that the guest cations exhibit a long-range mobility and that their mobility is governed by their size relative to the size of the cryptand molecules. On the other hand, the valence of the guest cations seems to play a minor role for the mobility. These results are discussed in comparison to the properties of conventional solid cationic conductors. (c) 2008 Elsevier B.V. All rights reserved.



How to cite
APA: Puchta, R., Roling, B., Scheurer, A., Weiskopf, V., Hampel, F., van Eikema Hommes, N., & Hummel, H.-U. (2008). Bicyclic diironcryptates with mobile guest cations: A new class of solid ionic conductors. Solid State Ionics, 179(13-14), 489-494. https://dx.doi.org/10.1016/j.ssi.2008.02.060

MLA: Puchta, Ralph, et al. "Bicyclic diironcryptates with mobile guest cations: A new class of solid ionic conductors." Solid State Ionics 179.13-14 (2008): 489-494.

BibTeX: Download


External Organisations
Share link
Last updated on 2017-09-19 at 03:17
PDF downloaded successfully