Öchsner E, Schneider M, Meyer C, Haumann M, Wasserscheid P (2011)
Publication Type: Journal article
Publication year: 2011
Publisher: Elsevier
Book Volume: 399
Pages Range: 35--41
Volume: 399
Issue: 1-2
Journal Issue: 1-2
DOI: 10.1016/j.apcata.2011.03.038
In the last years Supported Ionic Liquid Phase (SILP) catalysis has attracted growing interest for continuous gas phase reactions. The concept combines in a unique manner the advantages of traditional homogeneous and heterogeneous catalysis by making use of the extremely low vapor pressure of an ionic liquid film on support. In this way, continuous gas phase reactions with macroscopically solid but microscopically homogeneous catalyst materials have been successfully realized. However---so far---continuous gas-phase SILP catalysis has only been demonstrated for reactions with relatively simple selectivity problems (such as, regioselectivity, chemoselectivity). This study demonstrates the successful application of a SILP catalyst in continuous gas phase asymmetric hydrogenation. The hydrogenation of methyl acetoacetate (MAA) is presented using an immobilized dibromo[3-(2,5-(2R,5R)-dimethylphospholanyl-1)-4-di-o-tolylphosphino-2,5-dimethylthio-phene]-ruthenium (Ru1Br2) catalyst.
APA:
Öchsner, E., Schneider, M., Meyer, C., Haumann, M., & Wasserscheid, P. (2011). Challenging the scope of continuous, gas-phase reactions with supported ionic liquid phase (SILP) catalysts-Asymmetric hydrogenation of methyl acetoacetate. Applied Catalysis A-General, 399(1-2), 35--41. https://dx.doi.org/10.1016/j.apcata.2011.03.038
MLA:
Öchsner, Eva, et al. "Challenging the scope of continuous, gas-phase reactions with supported ionic liquid phase (SILP) catalysts-Asymmetric hydrogenation of methyl acetoacetate." Applied Catalysis A-General 399.1-2 (2011): 35--41.
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