Ambiphilicity: A Characteristic Reactivity Principle of Pi-Bound Phosphorus Heterocycles

Clark T, Toepffer C, Heinemann FW, Hennemann M, Zenneck U (2002)

Publication Type: Journal article

Publication year: 2002

Journal

Angewandte Chemie International Edition Wiley

Publisher: Wiley-VCH Verlag

Book Volume: 41

Pages Range: 4047-4052

Journal Issue: 21

DOI: 10.1002/1521-3773(20021104)41:21<4047::AID-ANIE4047>3.0.CO;2-4

Abstract

Bicycles made in crystals: The phosphorus atoms of the: π ligand 1,3-diphosphete turn out to be ambiphilic centers with pronounced intramolecular reactivity. This property results in a temperature-dependent bond formation in [(2,4-di-tBu-1,3-diphosphete)3Mo], which is found to be a topotactic reaction in the single crystal (see scheme). This new reactivity principle can be used to explain a series of complex interligand bond-formation reactions of phosphorus heterocycles.

Authors with CRIS profile

Timothy Clark Computer-Chemie-Centrum Christian Toepffer Naturwissenschaftliche Fakultät Frank Wilhelm Heinemann Lehrstuhl für Anorganische und Allgemeine Chemie Matthias Hennemann Computer-Chemie-Centrum Ulrich Zenneck Naturwissenschaftliche Fakultät

How to cite

APA:

Clark, T., Toepffer, C., Heinemann, F.W., Hennemann, M., & Zenneck, U. (2002). Ambiphilicity: A Characteristic Reactivity Principle of Pi-Bound Phosphorus Heterocycles. Angewandte Chemie International Edition, 41(21), 4047-4052. https://dx.doi.org/10.1002/1521-3773(20021104)41:21<4047::AID-ANIE4047>3.0.CO;2-4

MLA:

Clark, Timothy, et al. "Ambiphilicity: A Characteristic Reactivity Principle of Pi-Bound Phosphorus Heterocycles." Angewandte Chemie International Edition 41.21 (2002): 4047-4052.

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