Journal article


Modelling the curing process in magneto-sensitive polymers: Rate-dependence and shrinkage


Publication Details
Author(s): Mokarram H, Saxena P, Steinmann P
Publisher: Elsevier
Publication year: 2015
Volume: 74
Pages range: 108-121
ISSN: 0020-7462
Language: English

Abstract

This paper deals with a phenomenologically motivated magneto-viscoelastic coupled finite strain framework for simulating the curing process of polymers under the application of a coupled magneto-mechanical load. Magneto-sensitive polymers are prepared by mixing micron-sized ferromagnetic particles in uncured polymers. Application of a magnetic field during the curing process causes the particles to align and form chain-like structures lending an overall anisotropy to the material. The polymer curing is a viscoelastic complex process where a transformation from fluid to solid occurs in the course of time. During curing, volume shrinkage also occurs due to the packing of polymer chains by chemical reactions. Such reactions impart a continuous change of magneto-mechanical properties that can be modelled by an appropriate constitutive relation where the temporal evolution of material parameters is considered. To model the shrinkage during curing, a magnetic-induction-dependent approach is proposed which is based on a multiplicative decomposition of the deformation gradient into a mechanical and a magnetic-induction-dependent volume shrinkage part. The proposed model obeys the relevant laws of thermodynamics. Numerical examples, based on a generalised Mooney–Rivlin energy function, are presented to demonstrate the model capacity in the case of a magneto-viscoelastically coupled load.



How to cite
APA: Mokarram, H., Saxena, P., & Steinmann, P. (2015). Modelling the curing process in magneto-sensitive polymers: Rate-dependence and shrinkage. International Journal of Non-Linear Mechanics, 74, 108-121. https://dx.doi.org/doi:10.1016/j.ijnonlinmec.2015.04.008

MLA: Mokarram, Hossain, Prashant Saxena, and Paul Steinmann. "Modelling the curing process in magneto-sensitive polymers: Rate-dependence and shrinkage." International Journal of Non-Linear Mechanics 74 (2015): 108-121.

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