Journal article
(Original article)


Transition metal complexes bearing a 2,2-bis(3,5-dimethylpyrazol-1-yl) propionate ligand: One methyl more matters


Publication Details
Author(s): Türkoglu G, Heinemann F, Burzlaff N
Publisher: Royal Society of Chemistry
Publication year: 2011
Volume: 40
Journal issue: 17
Pages range: 4678-4686
ISSN: 1477-9226
eISSN: 1477-9234

Abstract

The new N,N,O ligand 2,2-bis(3,5-dimethylpyrazol-1-yl)propionic acid (2,2-Hbdmpzp) (2) and its transition metal complexes [Mn(2,2-bdmpzp)(CO) ] (3), [Re(2,2-bdmpzp)(CO) ] (4), [Cu(2,2-bdmpzp) ] (5), and [Ru(2,2-bdmpzp)Cl(L)(PPh )] [L = PPh (6), N (7), CO (8a/b), SO (9a/b)] have been synthesized, characterized and compared to analogous complexes bearing a bis(3,5-dimethylpyrazol-1-yl)acetic acid. It was found that the additional methyl group has a remarkable influence on the stability and reactivity of transition metal complexes. © 2011 The Royal Society of Chemistry.



How to cite
APA: Türkoglu, G., Heinemann, F., & Burzlaff, N. (2011). Transition metal complexes bearing a 2,2-bis(3,5-dimethylpyrazol-1-yl) propionate ligand: One methyl more matters. Dalton Transactions, 40(17), 4678-4686. https://dx.doi.org/10.1039/c1dt00022e

MLA: Türkoglu, Gazi, Frank Heinemann, and Nicolai Burzlaff. "Transition metal complexes bearing a 2,2-bis(3,5-dimethylpyrazol-1-yl) propionate ligand: One methyl more matters." Dalton Transactions 40.17 (2011): 4678-4686.

BibTeX: Download
Share link
Last updated on 2017-11-21 at 01:34
PDF downloaded successfully