Journal article
(Original article)


Heteroscorpionate complexes based on bis(3,5-di-tert-butylpyrazol-1-yl) dithioacetate


Publication Details
Author(s): Tampier S, Burzlaff N
Publisher: International Union of Crystallography
Publication year: 2013
Volume: 69
Journal issue: 9
Pages range: 981-985
ISSN: 0108-2701

Abstract

The heteroscorpionate ligand bis(3,5-di-tert-butylpyrazol-1-yl) dithioacetate (bdtbpzdta) has been synthesized by reacting bis(3,5-di-tert- butylpyrazol-1-yl)methane with n-BuLi and CS. The ligand was isolated as [bis(3,5-di-tert-butylpyrazol-1-yl)dithioacetato](tetrahydrofuran) lithium(I) tetrahydrofuran monosolvate, [Li(CHN S)(CHO)]·C HO or [Li(bdtbpzdta)(THF)]·THF, in which the lithium cation is bound by the κ N,N',S-coordinated heteroscorpionate ligand. A similar coordination mode is observed for a zinc chloride complex bearing the bdtbpzdta ligand, namely [bis(3,5-di-tert- butylpyrazol-1-yl)dithioacetato]chloridozinc(II), [Zn(CH NS)Cl] or [Zn(bdtbpzdta)Cl], which exhibits κ N,N',S-coordination and resembles the active site of zinc-containing peptide deformylases (PDFs). © 2013 International Union of Crystallography.



How to cite
APA: Tampier, S., & Burzlaff, N. (2013). Heteroscorpionate complexes based on bis(3,5-di-tert-butylpyrazol-1-yl) dithioacetate. Acta Crystallographica Section C: Crystal Structure Communications, 69(9), 981-985. https://dx.doi.org/10.1107/S0108270113021148

MLA: Tampier, Stefan, and Nicolai Burzlaff. "Heteroscorpionate complexes based on bis(3,5-di-tert-butylpyrazol-1-yl) dithioacetate." Acta Crystallographica Section C: Crystal Structure Communications 69.9 (2013): 981-985.

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