Thermodynamic Analysis of Chemical Hydrogen Storage: Energetics of Liquid Organic Hydrogen Carrier Systems Based on Methyl-Substituted Indoles

Vostrikov SV, Samarov AA, Turovtsev VV, Wasserscheid P, Müller K, Verevkin SP (2023)

Publication Type: Journal article

Publication year: 2023

Journal

Materials MDPI

Book Volume: 16

Article Number: 2924

Journal Issue: 7

DOI: 10.3390/ma16072924

Abstract

Liquid organic hydrogen carriers can store hydrogen in a safe and dense form through covalent bonds. Hydrogen uptake and release are realized by catalytic hydrogenation and dehydrogenation, respectively. Indoles have been demonstrated to be interesting candidates for this task. The enthalpy of reaction is a crucial parameter in this regard as it determines not only the heat demand for hydrogen release, but also the reaction equilibrium at given conditions. In this work, a combination of experimental measurements, quantum chemical methods and a group-additivity approach has been applied to obtain a consistent dataset on the enthalpies of formation of different methylated indole derivatives and their hydrogenated counterparts. The results show a namable influence of the number and position of methyl groups on the enthalpy of reaction. The enthalpy of reaction of the overall hydrogenation reaction varies in the range of up to 18.2 kJ·mol⁻¹ (corresponding to 4.6 kJ·mol(H2)⁻¹). The widest range of enthalpy of reaction data for different methyl indoles has been observed for the last step (hydrogenation for the last double bond in the five-membered ring). Here a difference of up to 7.3 kJ·mol(H2)⁻¹ between the highest and the lowest value was found.

Authors with CRIS profile

Peter Wasserscheid Lehrstuhl für Chemische Reaktionstechnik

Involved external institutions

Samara State Technical University (SSTU) / Samara Polytech / Сама́рский госуда́рственный техни́ческий университе́т (СамГТУ)

Russian Federation (RU) Saint Petersburg State University (SPbU) / Санкт-Петербургский государственный университет (СПбГУ)

Russian Federation (RU) Tver State Medical University (TverSMU, TSMA) / Тверской государственный медицинский Университет

Russian Federation (RU) Forschungszentrum Jülich / Research Centre Jülich (FZJ)

Germany (DE) Universität Rostock

Germany (DE)

How to cite

APA:

Vostrikov, S.V., Samarov, A.A., Turovtsev, V.V., Wasserscheid, P., Müller, K., & Verevkin, S.P. (2023). Thermodynamic Analysis of Chemical Hydrogen Storage: Energetics of Liquid Organic Hydrogen Carrier Systems Based on Methyl-Substituted Indoles. Materials, 16(7). https://doi.org/10.3390/ma16072924

MLA:

Vostrikov, Sergey V., et al. "Thermodynamic Analysis of Chemical Hydrogen Storage: Energetics of Liquid Organic Hydrogen Carrier Systems Based on Methyl-Substituted Indoles." Materials 16.7 (2023).

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