High-Energy Computed Tomography as a Prospective Tool for In Situ Monitoring of Mass Transfer Processes inside High-Pressure Reactors-A Case Study on Ammonothermal Bulk Crystal Growth of Nitrides including GaN

Schimmel S, Salamon M, Tomida D, Neumeier S, Ishiguro T, Honda Y, Chichibu SF, Amano H (2022)

Publication Language: English

Publication Type: Journal article

Publication year: 2022

Journal

Materials MDPI

Book Volume: 15

Pages Range: 6165

Article Number: 6165

Journal Issue: 17

DOI: 10.3390/ma15176165

Open Access Link: https://doi.org/10.3390/ma15176165

Abstract

For the fundamental understanding and the technological development of the ammonothermal method for the synthesis and crystal growth of nitrides, an in situ monitoring technique for tracking mass transport of the nitride throughout the entire autoclave volume is desirable. The feasibility of using high-energy computed tomography for this purpose was therefore evaluated using ex situ measurements. Acceleration voltages of 600 kV were estimated to yield suitable transparency in a lab-scale ammonothermal setup for GaN crystal growth designed for up to 300 MPa operating pressure. The total scan duration was estimated to be in the order of 20 to 40 min, which was sufficient given the comparatively slow crystal growth speed in ammonothermal growth. Even shorter scan durations or, alternatively, lower acceleration voltages for improved contrast or reduced X-ray shielding requirements, were estimated to be feasible in the case of ammonoacidic growth, as the lower pressure requirements for this process variant allow for thinned autoclave walls in an adapted setup designed for improved X-ray transparency. Promising nickel-base and cobalt-base alloys for applications in ammonothermal reactors with reduced X-ray absorption in relation to the maximum operating pressure were identified. The applicability for the validation of numerical simulations of the growth process of GaN, in addition to the applicability of the technique to further nitride materials, as well as larger reactors and bulk crystals, were evaluated.

Authors with CRIS profile

Saskia Schimmel Lehrstuhl für Elektronische Bauelemente Steffen Neumeier Lehrstuhl für Werkstoffwissenschaften (Allgemeine Werkstoffeigenschaften)

Involved external institutions

Tohoku University JP Japan (JP) Nagoya University / 名古屋大学 JP Japan (JP) Fraunhofer-Institut für Integrierte Schaltungen (IIS) DE Germany (DE)

How to cite

APA:

Schimmel, S., Salamon, M., Tomida, D., Neumeier, S., Ishiguro, T., Honda, Y.,... Amano, H. (2022). High-Energy Computed Tomography as a Prospective Tool for In Situ Monitoring of Mass Transfer Processes inside High-Pressure Reactors-A Case Study on Ammonothermal Bulk Crystal Growth of Nitrides including GaN. Materials, 15(17), 6165. https://doi.org/10.3390/ma15176165

MLA:

Schimmel, Saskia, et al. "High-Energy Computed Tomography as a Prospective Tool for In Situ Monitoring of Mass Transfer Processes inside High-Pressure Reactors-A Case Study on Ammonothermal Bulk Crystal Growth of Nitrides including GaN." Materials 15.17 (2022): 6165.

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