Expandable Graphite, Aluminum Diethylphospinate and Melamine Polyphosphate as Flame Retarding System in Glass Fiber-Reinforced PA6

Tomiak F, Schoeffel A, Rathberger K, Drummer D (2022)

Publication Type: Journal article

Publication year: 2022

Journal

Polymers MDPI

Book Volume: 14

Journal Issue: 6

DOI: 10.3390/polym14061263

Abstract

A flame retardant system based on expandable graphite (EG), aluminum diethylphosphinate (AlPI) and melamine polyphosphate (MPP) was investigated in glass fiber- (GF) reinforced polyamide 6 (PA6). Burning characteristics were evaluated via cone calorimeter, limiting oxygen index (LOI) and UL-94 tests. Thermogravimetric analysis (TGA) and coupled Fourier transform infrared spectroscopy (FTIR) was used to investigate the decomposition process as well as flame retardant modes of actions. Specifically, in the cone calorimeter tests, formulations containing EG showed excellent flame retardant properties for non-reinforced and reinforced PA6. The best performance was achieved for 25 wt.% glass fiber-reinforced PA6 containing solely 20 wt.% EG, corresponding to a measured pHRR of 134 kW/m(2) and a total smoke production of 1.2 m(2). Higher glass fiber contents of 45 wt.% (30 vol.%) revealed a lower char volume, which was attributed to both the limited space available for expansion and the sheer-induced reduction in particle size during processing. All of the reinforced PA6 formulations only achieved V2 classifications, but this was at low filling degrees (10 wt.%) for both net EG or EG/AlPi/MPP combinations. For GF-reinforced PA6 containing EG/AlPi/MPP mixtures, a synergistic effect was found to improve the oxygen index up to 30.6%.

Authors with CRIS profile

Florian Tomiak Lehrstuhl für Kunststofftechnik Dietmar Drummer Lehrstuhl für Kunststofftechnik

Related research project(s)

Flame Retardant Compounds – New Generation Ex-pandable Graphite for High Performance Materials (HiPeX) (HiPeX) Sept. 1, 2020 - Feb. 28, 2022

Involved external institutions

Georg H. LUH GmbH DE Germany (DE)

How to cite

APA:

Tomiak, F., Schoeffel, A., Rathberger, K., & Drummer, D. (2022). Expandable Graphite, Aluminum Diethylphospinate and Melamine Polyphosphate as Flame Retarding System in Glass Fiber-Reinforced PA6. Polymers, 14(6). https://dx.doi.org/10.3390/polym14061263

MLA:

Tomiak, Florian, et al. "Expandable Graphite, Aluminum Diethylphospinate and Melamine Polyphosphate as Flame Retarding System in Glass Fiber-Reinforced PA6." Polymers 14.6 (2022).

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