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Rheological properties of electron beam-irradiated polypropylenes with different molar masses

Auhl D, Stadler F, Münstedt H (2012)

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Publication Type: Journal article

Publication year: 2012

Journal

Book Volume: 51

Pages Range: 979-989

Journal Issue: 11-12

DOI: 10.1007/s00397-012-0646-6

Abstract

Electron beam-irradiated polypropylene undergoes chain scission initiated by the loss of a proton. The resulting macroradicals can lead to branched molecules. However, the understanding of the influence of irradiation on the branching of polypropylene is still scarce. Therefore, this paper investigates structure-property relationships in such irradiated polymers. In general, irradiation yields long-chain branches, which develop from a star-like into a tree-like branching architecture with increasing dose. These conclusions can be drawn from the relation between the zero shear-rate viscosity η 0 and the weight average molar mass M w as well as from the elongational behavior. © 2012 Springer-Verlag.

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How to cite

APA:

Auhl, D., Stadler, F., & Münstedt, H. (2012). Rheological properties of electron beam-irradiated polypropylenes with different molar masses. Rheologica Acta, 51(11-12), 979-989. https://dx.doi.org/10.1007/s00397-012-0646-6

MLA:

Auhl, Dietmar, Florian Stadler, and Helmut Münstedt. "Rheological properties of electron beam-irradiated polypropylenes with different molar masses." Rheologica Acta 51.11-12 (2012): 979-989.

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